Particle
Induced
X
Ray
Emission
and
Mars
Exploration Rovers
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this
lesson
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Alpha Particle
Induced X Ray Emission
- APXS uses a variety of radiation techniques to determine
atomic nuclei
mass, including:
- Alpha particle
- Protons
- X-Ray
- Radioactive Currium is used as the alpha particle source
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Photo of Mars Pathfinder
with APXS highlighted in red
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Alpha
Particle
- Alpha particles (4He) are emitted from Curim source
- Using Rutherford’s laws for backscattering, the atomic mass of
the
nuclei can be determined
- Lighter elements absorb energy of alpha particle
- Heavier elements reflect energy of alpha particle of the same
energy
- Most useful in determining lighter elemental composition of a
sample
Proton*
- Alpha particles are absorbed by atomic nuclei producing protons
of a
defined energy
- Sodium, magnesium, silicon, aluminum, and sulfur detection
*Used only by Mars Pathfinder, subsequent Mar Exploration Rovers did
not
use
X-Ray
- Alpha particles ejected electrons from
the inner electron shell (K or L
shell)
- K series: ejection from K shell
- L series: ejection from L shell
- Outer shell electrons drop down to
fill vacancies emitting
energy.
- Only certain
transitions are allowed.
- Energy emitted is characteristic of an element:
Wavelength =
K/E
where E is the energy emitted & K
is a constant = 1.9865 x 10-16 nm
J
- The number and energy of X ray emitted are measured
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Results
- Rock sample from Barnacle Bill in Ares Vallis on Mars
- Unexpectedly high in silica and potassium; low in magnesium
compared to
martian soils and martian meteorites.
- Analysis indicates that sample rocks are andesitic
(volcanic)
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X-Ray
spectrum from
Barnacle Bill on Mars exhibiting a
diverse chemical composition (Reider 1997).
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References
R.
Rieder,
T.
Economou,
H.
Wänke,
A. Turkevich, J. Crisp, J.
Brückner, G. Dreibus, H. Y. McSween Jr. "The
Chemical Composition
of Martian Soil and Rocks Returned by the Mobile Alpha Proton X-ray
Spectrometer: Preliminary Results from the X-ray Mode."
Science
(1997). 278:1711-1774
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