Recent Publications

Time domain recent publications:

Yoo, Hyun S.; DeWitt, Merrick J.; Pate, Brooks H. Vibrational Dynamics of Terminal Acetylenes: I. Comparison of the Intramolecular Vibrational Energy Redistribution Rate of Gases and the Total Relaxation Rate of Dilute Solutions at Room Temperature. Journal of Physical Chemistry A (2004), 108(8), 1348-1364.

Yoo, Hyun S.; DeWitt, Merrick J.; Pate, Brooks H. Vibrational Dynamics of Terminal Acetylenes: II. Pathway for Vibrational Relaxation in Gas and Solution. Journal of Physical Chemistry A (2004), 108(8), 1365-1379.

Yoo, Hyun S.; McWhorter, David A.; Pate, Brooks H. Vibrational Dynamics of Terminal Acetylenes: III. Comparison of the Acetylenic C-H Stretch Intramolecular Vibrational-Energy Redistribution Rates in Ultracold Molecular Beams, Room-Temperature Gases, and Room-Temperature Dilute Solutions. Journal of Physical Chemistry A (2004), 108(8), 1380-1387.

Frequency domain recent publications:

Douglass, Kevin O.; Rees, Frances S.; Suenram, Richard D.; Pate, Brooks H.; Leonov, Igor. Rotational spectroscopy of the first excited state of the acetylenic C-H stretch of 3-fluoropropyne performed by infrared-Fourier transform microwave-microwave triple-resonance spectroscopy. Journal of Molecular Spectroscopy (2005), 230(1), 62-71.

Douglass, Kevin O.; Dian, Brian C.; Brown, Gordon G.; Johns, James E.; Nair, Pradeep M.; Pate, Brooks H.. Motional narrowing of the rotational spectrum of trifluoropropyne at 6550 cm-1 by intramolecular vibrational energy redistribution. Journal of Chemical Physics (2004), 121(14), 6845-6854.

Douglass, Kevin O.; Keske, John C.; Rees, Frances S.; Welch, Kevin; Yoo, Hyun S.; Pate, Brooks H.; Leonov, Igor; Suenram, R. D. Rotational spectroscopy of vibrationally excited states by infrared-Fourier transform microwave-microwave triple-resonance spectroscopy. Chemical Physics Letters (2003), 376(5,6), 548-556.

Keske, John C.; Rees, Frances S.; Suenram, R. D.; Pate, Brooks H.. Structure and vibrational dynamics of the halogen-substituted butynes HCºCCH2CH2X (X = F,Cl,Br) from molecular-beam high-resolution microwave and infrared spectroscopy. Physical Chemistry Chemical Physics (2003), 5(8), 1599-1609.

Keske, John C.; Pate, Brooks H.. Decoding the dynamical information embedded in highly mixed quantum states. Annual Review of Physical Chemistry (2000), 51 323-353.

Keske, John; McWhorter, David A.; Pate, Brooks H.. Molecular rotation in the presence of intramolecular vibrational energy redistribution. International Reviews in Physical Chemistry (2000), 19(3), 363-407.

Pate, Brooks H.. The rotational spectrum of a highly vibrationally mixed quantum state. I. Intramolecular vibrational energy redistribution (IVR) exchange narrowing of the rotational spectrum. Journal of Chemical Physics (1998), 109(11), 4396-4406.

Pate, Brooks H.. The rotational spectrum of a highly vibrationally mixed quantum state. II. The eigenstate-resolved spectroscopy analog to dynamic nuclear magnetic resonance spectroscopy. Journal of Chemical Physics (1999), 110(4), 1990-1999.